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I start using MS Office 2007 and also has Adobe Acrobat 8.0 install, I can print as PDF in MS Word 2003 but not with MS Office 2007. See below screen shots of error:

But in fact with MS Office 2007, Microsoft has provided an add-in for converting from DOC to PDF very easily, just download from:

After I install: SaveAsPDFandXPS.exe
I can convert by go to: Save As -> PDF or XPS
PDF loaded as expected!